Identification of marine and continental aerosol sources in Paris using high resolution aerosol mass spectrometry

authors

• Crippa Monica
• El Haddad Imad
• Slowik Jay G.
• Decarlo Peter F.
• Mohr Claudia
• Heringa Maarten F.
• Chirico Roberto
• Marchand Nicolas
• Sciare Jean
• Baltensperger Urs
• Prévôt André S. H.

document type

abstract

[1] Major summertime aerosol emission sources in Paris were assessed using a high resolution time-of-flight aerosol mass spectrometer (HR-ToF-AMS). The application of positive matrix factorization (PMF) to the highly mass and time-resolved AMS measurements allowed the identification of primary and secondary sources of organic (OA) and sulfate aerosols. Primary anthropogenic emissions contributed on average~27% (14.7% cooking, 12% traffic) to the total organic mass, while the major contribution to the organic fraction was associated with secondary formation products. Low-volatility oxygenated OA (LV-OOA, 25.2%) and semi-volatile oxygenated OA (SV-OOA, 32.4%) factors were classified as SOA. An additional component with high S : C and O : C ratios was identified and attributed to marine emissions (marine organic aerosol, MOA), owing to its high correlation with methanesulfonic acid (R 2 = 0.84) and contributing on average 15.7% to the total OA mass, even in the continental megacity of Paris. Non-sea salt sulfate was apportioned by including both organic and sulfate ions in the PMF data matrix. This allowed apportionment of submicron sulfate to continental versus marine sources. A detailed source apportionment of PM 1 combining AMS, aethalometer, and filter data is presented. Citation: Crippa, M., et al. (2013), Identification of marine and continental aerosol sources in Paris using high resolution aerosol mass spectrometry,

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